When A Porous Solid Retains Its Properties In Liquid Form

When A Porous Solid Retains Its Properties In Liquid Form

When a porous solid retains its properties in liquid form

Known for their exceptional porosity that enables the trapping or transport of molecules, metal-organic frameworks (MOFs) take the form of a powder, which makes them difficult to format. For the first time, an international team led by scientists from the Institut de recherche de Chimie Paris (CNRS/Chimie ParisTech ), and notably involving Air Liquide, has evidenced the surprising ability of a type of MOF to retain its porous properties in the liquid and then glass state. Published on October 9, 2017 in Nature Materials website, these findings open the way towards new industrial applications.

Metal-organic frameworks (MOFs) constitute a particularly promising class of materials. Their exceptional porosity makes it possible to store and separate large quantities of gas, or to act as a catalyst for chemical reactions. However, their crystalline structure implies that they are produced in powder form, which is difficult to store and use for industrial applications. For the first time, a team of scientists from the CNRS, Chimie ParisTech, Cambridge University, Air Liquide and the ISIS (UK) and Argonne (US) synchrotrons has shown that the properties of a zeolitic MOF were unexpectedly conserved in the liquid phase (which does not generally favor porosity). Then, after cooling and solidification, the glass obtained adopted a disordered, non-crystalline structure that also retained the same properties in terms of porosity. These results will enable the shaping and use of these materials much more efficiently than in powder form.

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The James Webb Space Telescope, or Webb, is our upcoming infrared space observatory, which will launch in 2019. It will spy the first luminous objects that formed in the universe and shed light on how galaxies evolve, how stars and planetary systems are born, and how life could form on other planets.  

A polish and shine that would make your car jealous

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All of the Webb telescope’s mirrors were polished to accuracies of approximately one millionth of an inch. The beryllium mirrors were polished at room temperature with slight imperfections, so as they change shape ever so slightly while cooling to their operating temperatures in space, they achieve their perfect shape for operations.

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The Midas touch

Engineers used a process called vacuum vapor deposition to coat Webb’s mirrors with an ultra-thin layer of gold. Each mirror only required about 3 grams (about 0.11 ounces) of gold. It only took about a golf ball-sized amount of gold to paint the entire main mirror!

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Before the deposition process began, engineers had to be absolutely sure the mirror surfaces were free from contaminants. 

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The engineers thoroughly wiped down each mirror, then checked it in low light conditions to ensure there was no residue on the surface.

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Inside the vacuum deposition chamber, the tiny amount of gold is turned into a vapor and deposited to cover the entire surface of each mirror.

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Primary, secondary, and tertiary mirrors, oh my!

Each of Webb’s primary mirror segments is hexagonally shaped. The entire 6.5-meter (21.3-foot) primary mirror is slightly curved (concave), so each approximately 1.3-meter (4.3-foot) piece has a slight curve to it.

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Those curves repeat themselves among the segments, so there are only three different shapes — 6 of each type. In the image below, those different shapes are labeled as A, B, and C.

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Webb’s perfectly circular secondary mirror captures light from the 18 primary mirror segments and relays those images to the telescope’s tertiary mirror.

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Learn more about the James Webb Space Telescope HERE, or follow the mission on Facebook, Twitter and Instagram.

Make sure to follow us on Tumblr for your regular dose of space: http://nasa.tumblr.com.


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8 years ago
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Read more.


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