Versatile superstructures composed of nanoparticles have recently been prepared using various disassembly methods. However, little information is known on how the structural disassembly influences the catalytic performance of the materials. Scientia Professor Rose Amal, Vice-Chancellor’s Research Fellow Hamid Arandiyan and a group from the Particles and Catalysis Research Group from the University of New South Wales (UNSW) School of Chemical Engineering have had their research address this issue published in Nature Communications.
The research team led by Dr Jason Scott and Prof Sean Smith in collaboration with Curtin University and Beijing University of Technology has developed a method that allows them to engineer crystals with a large fraction of reactive facets. An ordered mesostructured La0.6Sr0.4MnO3 (LSMO) perovskite catalyst was disassembled using a unique fragmentation strategy, whereby the newly-exposed (001) reactive faces at each fracture were more reactive towards methane oxidation than the regular (i.e. before disassembly)
It is of significant interest to use methane as an alternative fuel to coal and oil due to its high hydrogen to carbon ratio which provides comparatively lower greenhouse gas emissions. Commercial catalysts for methane combustion contain precious metals (e.g. Pt and Pd) which are of high cost and poor thermal stability (caused by agglomeration of the metal deposits). Using perovskite-type catalysts to replace noble metal supported catalysts for methane oxidation has attracted recent attention due to their excellent thermal stability. In their recently published article, the research team describes a simple fragmentation method to synthesise a novel three-dimensional hexapod mesostructured LSMO perovskite.
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The hydrogen in your body, present in every molecule of water, came from the Big Bang. There are no other appreciable sources of hydrogen in the universe. The carbon in your body was made by nuclear fusion in the interior of stars, as was the oxygen. Much of the iron in your body was made during supernovas of stars that occurred long ago and far away. The gold in your jewelry was likely made from neutron stars during collisions that may have been visible as short-duration gamma-ray bursts. Elements like phosphorus and copper are present in our bodies in only small amounts but are essential to the functioning of all known life. The featured periodic table is color coded to indicate humanity’s best guess as to the nuclear origin of all known elements. The sites of nuclear creation of some elements, such as copper, are not really well known and are continuing topics of observational and computational research.
Image Credit: Cmglee (Own work) CC BY-SA 3.0 or GFDL, via Wikimedia Commons
Chalcedony - Mamuju Area, Sulawesi Barat Province, Sulawesi Island, Indonesia
Native Gold with White Quartz
Eagle’s Nest Mine, Placer County, California
Exhibition
Radio waves, microwaves and even light itself are all made of electric and magnetic fields. The classical theory of electromagnetism was completed in the 1860s by James Clerk Maxwell. At the time, Maxwell’s theory was revolutionary, and provided a unified framework to understand electricity, magnetism and optics.
Now, new research led by LSU Department of Physics and Astronomy Assistant Professor Ivan Agullo, with colleagues from the Universidad de Valencia, Spain, advances knowledge of this theory. Their recent discoveries have been published in Physical Review Letters.
Maxwell’s theory displays a remarkable feature: it remains unaltered under the interchange of the electric and magnetic fields, when charges and currents are not present. This symmetry is called the electric-magnetic duality.
However, while electric charges exist, magnetic charges have never been observed in nature. If magnetic charges do not exist, the symmetry also cannot exist. This mystery has motivated physicists to search for magnetic charges, or magnetic monopoles. However, no one has been successful. Agullo and his colleagues may have discovered why.
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#SCOPENewYork 2016 | Exhibitor Highlight | Nil Gallery - Booth B05
[Ardan Ozmenoglu, Olive Tree, 2008, paint on glass, 31 x 31 in.]
@ardanozmenoglu
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Exchanges of identity in deep space
By reproducing the complexity of the cosmos through unprecedented simulations, a new study highlights the importance of the possible behaviour of very high energy photons
Like in a nail-biting thriller full of escapes and subterfuge, photons from far-off light sources, such as blazars, could go up against a continuous exchange of identity in their journey through the Universe. This is an operation that would allow these very tiny particles of light to escape an enemy which, if encountered, would annihilate them. This is the phenomenon studied by a group of researchers from the University of Salento, Bari, the National Institute for Nuclear Physics (INFN), the National Institute for Astrophysics (INAF) and SISSA thanks to brand new simulation models that reproduce the complexity of the cosmos as never before. Normally, very high energy photons (gamma rays) should “collide” with the background light emitted by galaxies transformed into pairs of matter and antimatter particles, as envisaged by the Theory of Relativity. For this reason, the sources of very high energy gamma rays should appear significantly less bright than what is observed in many cases.
A possible explanation for this surprising anomaly is that light photons are transformed into hypothetical weakly-interacting particles, “axions” which, in turn, would change into photons, all due to the interaction with magnetic fields. With these metamorphoses, a part of the photons would escape interaction with the intergalactic background light that would make them disappear. The importance of this process is emphasised by the study published on Physical Review Letters, which re-created an extremely refined model of the Cosmic Web, a network of filaments composed of gas and dark matter present throughout the Universe and of its magnetic fields. The aforementioned effects are now awaiting comparison with those obtained experimentally through Cherenkov Telescope Array new generation telescopes.
In this research, through complex and unprecedented computer simulations made at the CSCS Supercomputing Centre in Lugano, scholars have reproduced the so-called Cosmic Web and the magnetic fields associated with this to investigate the possibility, advanced from previous theories, that photons from a light source are transformed into axions, hypothetical elementary particles, on interacting with an extragalactic magnetic field. Axions could then be retransformed into photons by interacting with other magnetic fields. Researchers Daniele Montanino, Franco Vazza, Alessandro Mirizzi and Matteo Viel explain: “Photons from luminous bodies disappear when they encounter extragalactic background light (EBL). But if on their journey they head into these transformations as envisaged by these theories, it would explain why, in addition to giving very important information on processes that occur in the universe, distant celestial bodies are brighter than expected from an observation on Earth. These changes would, in fact, enable a greater number of photons to reach the Earth”.
In the simulations made by scientists, thanks to the wealth of magnetic fields present in the Cosmic Web’s filaments recreated with the simulations, the conversion phenomenon would seem much more relevant than predicted by previous models: “Our simulations reproduce a very realistic picture of the cosmos’ structure. From what we have observed, the distribution of the Cosmic Web envisaged by us would markedly increase the probability of these transformations”. The next step in the research? To compare simulation results with the experimental data obtained through the use of the Cherenkov Telescope Array Observatories detectors, the new-generation astronomical observatories, one of which is positioned in the Canary Islands and the other in Chile, that will study the Universe through very high energy gamma rays.
IMAGE….Through complex computer simulations, researchers have reproduced the so-colled Comsc Web and its magnetic fields Credit Vazza F., Bruggen M. Gheller, C., Wang P.
David Spriggs, Dark Matter.